6/16
To see this notice that a tail could occur on the first flip and then on any of the next three flips. So there are three ways that can happen.
Or, it could occur on the second flip and then on any of the two remaining flips. That's two more ways.
Or, it could occur on the third and on the 4th flips.
So, 3 + 2 + 1 = 6
And there are 2 outcomes possible on each flip, so the total number of outcomes is just 2*2*2*2 = 16
Thus, 6/16